Course Unit Code | 617-2005/02 |
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Number of ECTS Credits Allocated | 6 ECTS credits |
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Type of Course Unit * | Compulsory |
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Level of Course Unit * | First Cycle |
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Year of Study * | Second Year |
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Semester when the Course Unit is delivered | Winter Semester |
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Mode of Delivery | Face-to-face |
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Language of Instruction | Czech |
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Prerequisites and Co-Requisites | |
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| Prerequisities | Course Unit Code | Course Unit Title |
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| 617-2001 | Chemistry I. |
| 617-2002 | Chemistry II. |
Name of Lecturer(s) | Personal ID | Name |
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| PAV33 | Ing. Jan Pavelka, ING.PAED.IGIP |
| KUL37 | doc. Ing. Lenka Kulhánková, Ph.D. |
Summary |
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The review of the key principles of the organic chemistry, modern methods of organic synthesis and organic analysis, as well as extension of the knowledge about the most important groups of organic compounds. |
Learning Outcomes of the Course Unit |
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- to define the binding properties of carbon,
- to detect intermolecular interactions and their effect on the melting point, the boiling point and the solubility of organic compounds,
- to define the separation of organic compounds into groups,
- to know the nomenclature of organic compounds,
- to describe the relationship between structure and properties of organic compounds,
- to describe the physical properties of hydrocarbons and their derivatives,
- to describe the reactivity of hydrocarbons and their derivatives,
- to describe the most common hydrocarbons and their derivatives,
- to define the basic groups, structure, properties and methods of preparation for polymeric substances.
Acquired knowledge:
- the ability to define a core group of organic compounds,
- the ability to determine the name of organic compounds,
- the ability to characterize the relationship between structure and properties of organic substances,
- the ability to characterize the reactions of organic compounds.
Acquired skills:
- the ability to apply theoretical knowledge points to selected technological processes,
- the ability to use basic laboratory techniques (filtration, recrystallization, distillation, decantation, cooling, etc.),
- the ability to use basic methods of preparing organic compounds (esterification, diazotization, etc.).
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Course Contents |
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Lectures
1. Introduction into the organic chemistry. History of organic chemistry. Bonding power of carbon (molecular orbitals, and bond, energy of bond, polarity of bond, hybridization, effects of electron). Relation between the structure and the properties of substances. Intermolecular interaction (van der Waals interaction, interaction of dipole, hydrogen bonds) and their influence on the melting temperature, boiling temperature and solubility.
2. Principles of stereochemistry of organic compounds. Drawing organic molecules (types of formulae, projection, models, 3D-shape of molecules). Polymerism and isomerism (constitutional, geometric, enantiomeric). The conformation of organic compounds.
3. Chemical reactions of organic compounds. Classification of organic reactions. Homolysis and heterolysis. Electrophilic and nucleophilic agents. Aliphatic and alicyclic hydrocarbons. Nomenclature of saturated hydrocarbons. Radical substitution. Cracking (catalyzed and uncatalyzed) and isomerization. Fischer-Tropsch synthesis. Resources of hydrocarbons and their application.
4. Unsaturated hydrocarbons. Radical and ion addition on double bond. Elimination reactions. Resources of unsaturated hydrocarbons and their industrial application.
5. Aromatic compounds. Delocalization of electrons. Electrophilic aromatic substitution (nitration, sulfonation, alkylation, acylation, halogenation) and others reactions. Resources of aromates and their industrial application. Toxicity of polyaromatic compounds.
6. Derivatives of hydrocarbons. Halogen derivatives. Physical properties, toxicity and application. Synthesis and important reactions.
7. Nitrogen derivatives of hydrocarbons (nitrocompounds, amines, diazonium salts, azocompounds). Physical properties, toxicity and application. Synthesis and important reactions. Alkaloids.
8. Sulfur derivatives of hydrocarbons (thioalcohols and thiophenols, sulfides, sulfonic acids). Physical properties and application. Synthesis and important reactions. Detergents.
9. Oxygen derivatives of hydrocarbons. Alcohols and phenols. Ethers. Physical properties, toxicity and application. Synthesis and important reactions.
10. Carbonyl compounds (aldehydes and ketones). Physical properties, toxicity and application. Synthesis and important reactions. Organometallic compounds. Reactivity, toxicity and application. Grignard reagents and their reactions.
11. Carboxylic acids. Physical properties and application. Synthesis and important reactions (acidity versus structure, neutralization, esterification, decarboxylation).
12. Substitution derivatives of carboxylic acids. Halogen-, Hydroxy-, Oxo, and Amino-acids. Physical properties and application. Synthesis and important reactions.
13. Functional derivatives of carboxylic acids. Acyl halides. Anhydrides. Esters. Amides. Nitriles. Physical properties, toxicity and application. Synthesis and important reactions. Derivatives of carbonic acid (phosgene, urea and their sulfur analogues).
14. Polymers (types, structure, properties, basic reactions of polymers preparation, overview of technically most important polymers).
Theoretical tutorials
- Introductory information (schedule of the seminar, the conditions for obtaining credit and recommended literature). Entering of seminar papers. Bonding power of carbon.
- Structure, formula, model. Inference of molecular formula, rational formula and structural formula. Determination of isomerism type for given compounds.
- Nomenclature of organic compounds.
- Nomenclature of organic compounds.
- Nomenclature of organic compounds.
- Nomenclature of organic compounds.
- Nomenclature of organic compounds.
Experimental work in labs
- Work safety in the laboratory, introduction to laboratory exercises, basic informations about exercises and requirements for laboratory protocols processing. Preparation of iodoform.
- Preparation of 1-nitronaphtalene.
- Preparation of 4-nitroaniline.
- Preparation of para red.
- Preparation of fumaric acid.
- Preparation of acetylsalicylic acid.
- Preparation of ethyl formate. |
Recommended or Required Reading |
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Required Reading: |
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MCMURRY, John. Organic chemistry. 6th ed. Belmont: Thomson Brooks/Cole, c2004. ISBN 0-534-38999-6.
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MCMURRY, John. Organická chemie. Přeložil Jaroslav JONAS. V Brně: VUTIUM ; V Praze, 2007. ISBN 978-80-214-3291-8.
WAISSER, Karel. Nové české názvosloví organické chemie. Praha: Karolinum, 2002. ISBN 80-246-0590-2.
MCMURRY, John. Organic chemistry. 6th ed. Belmont: Thomson Brooks/Cole, c2004. ISBN 0-534-38999-6.
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Recommended Reading: |
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SOLOMONS, T. W. Graham a Craig B. FRYHLE. Organic chemistry [CD-ROM]. 8th ed. Hoboken: Wiley, c2004. ISBN 0-471-41799-8.
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SVOBODA, Jiří a kol. Organická chemie I. VŠCHT Praha, 2005. ISBN 80-7080-561-7.
FIKR, Jaroslav a Jaroslav KAHOVEC. Názvosloví organické chemie. 3. vyd. Olomouc: Agentura Rubico, 2008. ISBN 978-80-7346-088-4.
SOLOMONS, T. W. Graham a Craig B. FRYHLE. Organic chemistry [CD-ROM]. 8th ed. Hoboken: Wiley, c2004. ISBN 0-471-41799-8.
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Planned learning activities and teaching methods |
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Lectures, Tutorials, Experimental work in labs |
Assesment methods and criteria |
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Task Title | Task Type | Maximum Number of Points (Act. for Subtasks) | Minimum Number of Points for Task Passing |
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Credit and Examination | Credit and Examination | 100 (100) | 51 |
Credit | Credit | 30 | 16 |
Examination | Examination | 70 (70) | 35 |
Písemná zkouška | Written examination | 40 | 21 |
Ústní zkouška | Oral examination | 30 | 14 |