The subject deals with spectrometry with emphasis on main spectroscopic parameters, such as quantum state populations, Einstein’s theory of spectral transitions, Planck’s law of absorption and emission of gases, principles of spectral character of absorption and emission, mechanisms causing the widening of lines, line shapes as information source, spectral line intensity, position and widening, radiative transfer equation and its special cases, theoretical principles of quantitative analysis, theory of spectroscopic experiment and basic principles of experimental methods in spectroscopy, microwave spectroscopy, rotational spectra and structure of molecules, vibrational spectroscopy, normal coordinates and symmetry coordinates, IR and Raman spectroscopy applications. Furthermore, it includes spectroscopic methods as analytical tools. It is above all a case of fundamentals of methods and their advantages and disadvantages when used in atmospheric research, fire protection and safety and security engineering, characterization of methods according to the spectral range - UV/VIS, infrared and microwave spectral regions, characterization of methods according to the type of detection – local and remote detection – measurement at the Earth’s surface, satellite measurement, lidar measurement, aircraft and balloon campaigns. Spectroscopic methods for lower troposheric research and upper troposheric and lower stratospheric research. It is a case of application in simulated and real atmosphere; international projects: MIPAS (Michelson Interferometer for Passive Atmospheric Sounding being placed onboard the satellite ENVISAT), ODIN satellite submillimeter atmospheric spectroscopy, NDSC (The Network for Detection of Stratospheric Change). Significant aspects of satellite measurements and generally “remote sensing” systems for safety and security research.
Spektroskopické metody v požární ochraně a bezpečnostním inženýrství (SM)
| Type of study | Doctoral |
|---|---|
| Language of instruction | English |
| Code | 030-0922/02 |
| Abbreviation | SM |
| Course title | Spektroskopické metody v požární ochraně a bezpečnostním inženýrství (SM) |
| Credits | 10 |
| Coordinating department | Department of Fire Protection |
| Course coordinator | prof. Ing. Zdeněk Zelinger, CSc. |
Subject syllabus
Literature
J.M. Hollas: High Resolution Spectroscopy, Butterworths, London 1982. P.F. Bernath: Spectra of Atoms and Molecules,Oxford University Press, New York, Oxford 1995. W. Demtröder: Laser Spectroscopy, Springer-Verlag, Berlin 1982 M. Lackner (Ed.): Lasers in Chemistry, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 2008 J. Orphal, C. E. Fellows, and P.-M. Flaud: "The visible absorption spectrum of NO3 measured by high-resolution Fourier-transform spectroscopy", Journal of Geophysical Research D 108 (D3), 4077, doi: 10.1029/2002JD002489, 2003. J. Orphal: "A critical review of the absorption cross-sections of O3 and NO2 in the 240-790 nm region", Journal of Photochemistry and Photobiology A: Chemistry 157, 185-209, 2003.
Advised literature
J.-M. Flaud, A. Perrin, J. Orphal, Q. Kou, P.-M. Flaud, C. Piccolo, and B. Carli: "New analysis of the v5+v9-v9 hot band of HNO3", Journal of Quantitative Spectroscopy and Radiative Transfer 77, 355-364, 2003. H. Kromminga, J. Orphal, P. Spietz, S. Voigt, and J. P. Burrows: "The temperature dependence (213-293 K) of the absorption cross-sections of OClO in the 340-450 nm region measured by Fourier-transform spectroscopy", Journal of Photochemistry and Photobiology A: Chemistry 157, 149-160, 2003. K. Bogumil, J. Orphal, T. Homann, S. Voigt, P. Spietz, O. C. Fleischmann, A. Vogel, M. Hartmann, H. Bov-ensmann, J. Frerick, and J. P. Burrows: "Measurements of molecular absorption spectra with the SCIAMACHY pre-flight model: instrument characterization and reference data for atmospheric remote-sensing in the 230-2380 nm region", Journal of Photochemistry and Photobiology A: Chemistry 157, 167-184, 2003.