Terminated in academic year 2014/2015

Thermodynamics of the Metals and Alloys

Type of study	Doctoral
Language of instruction	Czech
Code	516-0939/02
Abbreviation	TDKS
Course title	Thermodynamics of the Metals and Alloys
Credits	10
Coordinating department	Institute of Physics
Course coordinator	prof. Dr. RNDr. Jiří Luňáček

Subject syllabus

1. Thermodynamical base
1.1. Basic laws
1.2. Thermodynamic potentials

2. Phase equlibrium and phase diagrams
2.1. Phase rules, equlibrium
2.2. Phases diagrams and calculations

3. Statistical thermodynamic
3.1. Particle distribution
3.2. Basic statistic categories
3.3. Distribution laws
3.4. Entropy

4. Theory of solution
4.1. Regular solutions
4.2. Equations and approximations
4.3. Binar and ternary solutions

5. Ordering and disordering
5.1. Ordering and disordering in binar alloys
5.2. Gorski-Bragg-Williams approximation
5.3. Enthalpy and heat capacity

6. Estimation of alloys enthalpy
6.1. Miedema model
6.2. Model parametres and their interpretation
6.3. Calculation of the mixing enthalpy
6.4. Excess enthalpy and entropy of alloys

Literature

1. CENGEL, Y.A.; BOLES, M.A. Thermodynamics, an Engineering Approach.
New York: McGraw-Hill, 2002, 930 p. ISBN 0-07-238332-1.
2. GOKCEN, N. A. Statistical Thermodynamis of Alloys. New York: Plenum Press,
1986, 326 p. ISBN 0-306-42177-1.
3. RAO, Y. K. Stoichiometry and Thermodynamics of Metallurgical Processes.
Cambridge University Press, 1985, 957 p. ISBN 0 521 25856 1.
4. LUPIS, C. H. P. Chemical Thermodynamics of Materials. Elsevier Science Pub.
Co., Inc. 1983, 581 p. ISBN 0-444-00713X, 0-444-00779-2.

Doporučená literatura

1. BORG, R. J.; DIENES, G. J. The Physical Chemistry of Solids. London:
Academic Press, 1992, 584 p. ISBN 0-12-118420-X.
2. BOER, F. R.; DE - BOOM, R.; MATTENS, W.C. M. et al. Cohesion in Metals.
In: Boer, F. R. de - Pettifor, D. G. (eds.): Cohesion and Structure,
Vol. 1, Amsterdam: North-Holland Publ., 1988, 637 p. ISBN 0-444-87098-9.

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