1) Gases, ideal gas, equation of state of an ideal gas, special cases, real gases, critical state, Van der Waals equation of state, Abel equation, virial equation of state and virial coefficients, compressibility factor, fugacity.
2) Heat capacities of substances – definition, mean heat capacity, variation of heat capacities with temperature, difference in the molar heat capacities between the products and reactants, experimental calorimetric determination of heat capacity – principle of method.
3) The First law of thermodynamics, definition, signification, constant pressure heat, constant volume heat, enthalpy. Thermodynamic definition of molar heat capacities.
4) Heating and cooling of substances. Heats of reaction.
5) Thermochemistry laws. Theoretical calculation of reaction heats. Heat of combustion. Heat of explosion.
6) Variation of the reaction heat with temperature - Kirchhoff’s equations and their utilization. Adiabatic reaction temperature.
7) Adiabatic reaction temperature.
8) The second law of thermodynamics, entropy and its temperature dependence, entropy change of the reaction and its temperature dependence, entropy change - pressure and volume dependence.
9) Thermodynamic potentials – Helmholtz and Gibbs free energy, significance and application.
10) Helmholtz and Gibbs free energy – temperature dependence.
11) Partial molar quantities. The chemical potential.
12) Types of equilibrium constants for homogeneous nad heterogeneous chemical reactions. Van´t Hoff reaction isotherm. Degree of conversion.
13) Effect of temperature on chemical equilibrium - Van't Hoff reaction isobare and isochore.
14) Phase equilibrium. Gibbs phase rule, phase diagram of a one-component system (phase diagram for water). Evaporation of pure liquid. Clapeyron and Clausius-Clapeyron equation.
15) Solutions, Raoult’s law. Distillation, constant pressure and constant temperature phase diagram.
16) Transport processes, heat, matter and momentum transfer.
17) Chemical kinetics, basic terms - rate of chemical reaction, law of mass action, (Guldberg-Waage law), molecularity, order of reaction.
18) Kinetics of first-order reactions, reaction half-life.
19) Second-order reactions, nth-order reactions.
20) Mechanisms of chemical reactions, rate-determining steps in consecutive and parallel reactions.
21) Temperature dependence of the rate of a chemical reaction - Arrhenius equation. Activation energy of chemical reaction – temperature dependence.
22) Pressure dependence of the rate of a chemical reaction.
23) Effect of concentration on reaction rate.
24) Collision theory of reaction rate.
25) Activated-complex theory - theory of absolute reaction rates.
26) Principles of catalysis, effect of catalysts and inhibitors on chemical reaction rate.
27) Kinetics of heterogeneous chemical reactions - elementary reaction steps in heterogenous process, diffusion, laws of diffusion and mathematical solution.
28) Consecutive and parallel diffusion, diffusion folloved by chemical reaction on phase interface.
29) Adsorption, adsorption of gases on solid surfaces, Freundlich and Langmuir adsorption isotherm. Adsorption folloved by chemical reaction on phase interface.
30) Adsorption from liquid solutions, Gibbs adsorption isotherm.
31) Colloidal chemistry.
32) Mechanism of burning reaction, theory of chain reactions - mathematical solution of differential equations.
33) Ignition limit, first, second and third pressure ignition limit.
34) Theory of thermal autoignition, flame temperature, calculation and graphic methods of flame temperature determination.
35) Homogeneous and heterogeneous burning.. Kinetic and diffusion burning.
36) Adiabatic (theoretical) flame temperature.
37) Combustible composition and burning products. Specific combustion heat and specific caloric power.
38) Combustion of solid and liquid fuels. Amount of oxygen and air for burning..
39) Combustion of gaseous fuels. Amount of oxygen and air for burning.
40) Explosive substances, thermal decomposition.
41) Mechanism of explosive transformations, explosive burning, explosion time of second order, detonation.
42) Detonation, physico-mathematical model of detonation, detonation characteristics.
43) Explosive hazards. Theory of extinguishing, physico-chemical principles.
2) Heat capacities of substances – definition, mean heat capacity, variation of heat capacities with temperature, difference in the molar heat capacities between the products and reactants, experimental calorimetric determination of heat capacity – principle of method.
3) The First law of thermodynamics, definition, signification, constant pressure heat, constant volume heat, enthalpy. Thermodynamic definition of molar heat capacities.
4) Heating and cooling of substances. Heats of reaction.
5) Thermochemistry laws. Theoretical calculation of reaction heats. Heat of combustion. Heat of explosion.
6) Variation of the reaction heat with temperature - Kirchhoff’s equations and their utilization. Adiabatic reaction temperature.
7) Adiabatic reaction temperature.
8) The second law of thermodynamics, entropy and its temperature dependence, entropy change of the reaction and its temperature dependence, entropy change - pressure and volume dependence.
9) Thermodynamic potentials – Helmholtz and Gibbs free energy, significance and application.
10) Helmholtz and Gibbs free energy – temperature dependence.
11) Partial molar quantities. The chemical potential.
12) Types of equilibrium constants for homogeneous nad heterogeneous chemical reactions. Van´t Hoff reaction isotherm. Degree of conversion.
13) Effect of temperature on chemical equilibrium - Van't Hoff reaction isobare and isochore.
14) Phase equilibrium. Gibbs phase rule, phase diagram of a one-component system (phase diagram for water). Evaporation of pure liquid. Clapeyron and Clausius-Clapeyron equation.
15) Solutions, Raoult’s law. Distillation, constant pressure and constant temperature phase diagram.
16) Transport processes, heat, matter and momentum transfer.
17) Chemical kinetics, basic terms - rate of chemical reaction, law of mass action, (Guldberg-Waage law), molecularity, order of reaction.
18) Kinetics of first-order reactions, reaction half-life.
19) Second-order reactions, nth-order reactions.
20) Mechanisms of chemical reactions, rate-determining steps in consecutive and parallel reactions.
21) Temperature dependence of the rate of a chemical reaction - Arrhenius equation. Activation energy of chemical reaction – temperature dependence.
22) Pressure dependence of the rate of a chemical reaction.
23) Effect of concentration on reaction rate.
24) Collision theory of reaction rate.
25) Activated-complex theory - theory of absolute reaction rates.
26) Principles of catalysis, effect of catalysts and inhibitors on chemical reaction rate.
27) Kinetics of heterogeneous chemical reactions - elementary reaction steps in heterogenous process, diffusion, laws of diffusion and mathematical solution.
28) Consecutive and parallel diffusion, diffusion folloved by chemical reaction on phase interface.
29) Adsorption, adsorption of gases on solid surfaces, Freundlich and Langmuir adsorption isotherm. Adsorption folloved by chemical reaction on phase interface.
30) Adsorption from liquid solutions, Gibbs adsorption isotherm.
31) Colloidal chemistry.
32) Mechanism of burning reaction, theory of chain reactions - mathematical solution of differential equations.
33) Ignition limit, first, second and third pressure ignition limit.
34) Theory of thermal autoignition, flame temperature, calculation and graphic methods of flame temperature determination.
35) Homogeneous and heterogeneous burning.. Kinetic and diffusion burning.
36) Adiabatic (theoretical) flame temperature.
37) Combustible composition and burning products. Specific combustion heat and specific caloric power.
38) Combustion of solid and liquid fuels. Amount of oxygen and air for burning..
39) Combustion of gaseous fuels. Amount of oxygen and air for burning.
40) Explosive substances, thermal decomposition.
41) Mechanism of explosive transformations, explosive burning, explosion time of second order, detonation.
42) Detonation, physico-mathematical model of detonation, detonation characteristics.
43) Explosive hazards. Theory of extinguishing, physico-chemical principles.