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Thermodynamics of heterogeneous systems

Type of study Doctoral
Language of instruction Czech
Code 635-0940/01
Abbreviation THS
Course title Thermodynamics of heterogeneous systems
Credits 10
Coordinating department Department of Thermal Engineering
Course coordinator prof. Ing. Jozef Vlček, Ph.D.

Osnova předmětu

The first law of thermodynamics, the standard state, enthalpy, heat of reaction.
The heat capacity, heat of reaction dependence on temperature applications.
The second law of thermodynamics, entropy, energy functions F and G, the conditions of thermodynamic equilibrium.
1-component systems, the balance in them, and enantiotropní monotropní transformation. Polymorphic transformation first and 2 order.
The equilibrium constant of chemical reaction, its dependence on temperature. Alternative options determine the reaction enthalpy and Gibbs equilibrium constants. Applications for major types of reactions in heterogeneous systems.
Thermodynamic analysis of 2 - and 3-component systems.
Binary and ternary phase diagrams. Use of diagrams in the preparation of specific systems and applications of ceramic materials.
Richardson-Jeffesův diagram, solution reduction of oxides, nitrogen mutual stability and behavior under different partial pressure of oxygen, applications.

Povinná literatura

LEVIN, E. M. et al. Phase Diagrams for Ceramists. The Amer. Ceram. Soc., 1956-1991.

Doporučená literatura

[1] MOORE, W. K. Fyzikální chemie (český překlad). Praha : SNTL, 1981.
[2] ŠESTÁK, J. Měření termofyzikálních vlastností pevných látek. Praha : Academia, 1982.