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Terminated in academic year 2019/2020

Nanomaterials on the phyllosilicates base

Type of study Follow-up Master
Language of instruction English
Code 9360-0145/02
Abbreviation NBVS
Course title Nanomaterials on the phyllosilicates base
Credits 3
Coordinating department CNT - Nanotechnology Centre
Course coordinator prof. Ing. Gražyna Simha Martynková, Ph.D.

Subject syllabus

1. Structure and crystal chemistry of silicates. Classification of silicates.
2. Structure and chemistry of layered silicates.
3. Layer charge, cation exchange in the interlayer, exfoliation, delamination,
intercalation.
4. Layered silicates and water in the interlayer space. Hydratation, dehydratatiion
and rehydratation.
5. Serpentine-kaolinite group. Structural ordering of kaolinites. Thermal change.
6. Halloysite.
7. Kaolinite and halloysite as clay nanofillers to polymers.
8. Talc-pyrophyllite group. Structure and modification for practical use.
9. Smectites. Cations exchange, modifications procedures.
10. Smectites as nanomaterials with specific properties.
11. Vermiculites. Thermal coversion of structure. Influence of acids on structure.
12. Vermiculite intercalation with metal compounds and their characteristics.
13. Organovermiculites. Preparation and characterization.
14. Clay minerals-polymers nanocomposites.

Literature

MARTIN, R.T. (Charman), BAILEY, S.W., EBERL, D.D., FANNING, D.S., GUGGENHEIM, S., KODAMA, H., PEVEAR, D.R., ŚRODOŃ, J. a WICKS, F. J. 1991. Report of The Clay Minerals Society Nomenclature Committee: Revised Classification of Clay Materials. Clays Clay Miner., 39, 333-335.
VALÁŠKOVÁ, M., SIMHA MARTYNKOVÁ, G.: Vermiculite: structural properties and examples of the use. In: Clay Minerals in Nature, their Characterization, Modification and Application (M. Valášková and G. Simha Martynková, Eds.), InTech 2012, 209-238, ISBN 978-953-51-0738-5.

Advised literature

G. Simha Martynková, M. Valášková: Vermiculite in nanocomposites: In Encyclopedia of Nanoscience and Nanotechnology, 2nd Edition (H.S. Nalwa, editor), ASP 2011, Vol. 25, 119-145, ISBN: 1-58883-190-6.
Handbook of Clay Science Edited by F. Bergaya, B.K.G. Theng and G. Lagaly
Developments in Clay Science, Vol. 1, 2006 Elsevier Ltd., pp.1224, ISBN-10 0-08-044183-1