• Introduction to thermodynamics. The first thermodynamic law, expression for defined process conditions. Enthalpy, reaction heat, standard states.
• Calculation of reaction heat from enthalpy of formation. Calculation of reaction heat from combustion and dissolving enthalpy.
• The thermal capacity of substances. Dependence of reaction heat on temperature.
• The second thermodynamic law. Entropy. Linked formulation of 1. and 2. thermodynamic law.
• Dependence of entropy on state variables. Change of entropy during the phase changes and chemical reactions. Energetic function F and G and their dependence on state variables.
• Conditions of thermodynamic balance for specific systems. Partial molar quantities, Gibbs-Duhem equation.
• Balance in one-component system, Clapeyron equal. Clausius-Clapeyron equal, application.
• Equal constant of chemical reaction, its dependence on temperature.
• Gibbs phase law, application. Thermodynamic analyse of two-component system, binary phase diagrams.
• Rules of representation 3- and 4-component systems, ternary phase diagrams.
• Richardson-Jeffes’s diagram, mutual stability of oxides.
• Reduction of oxides by hydrogen and carbon oxide. Reduction of oxides by carbon. Stability of oxides with different partial pressure of oxygen.
• Calculation of reaction heat from enthalpy of formation. Calculation of reaction heat from combustion and dissolving enthalpy.
• The thermal capacity of substances. Dependence of reaction heat on temperature.
• The second thermodynamic law. Entropy. Linked formulation of 1. and 2. thermodynamic law.
• Dependence of entropy on state variables. Change of entropy during the phase changes and chemical reactions. Energetic function F and G and their dependence on state variables.
• Conditions of thermodynamic balance for specific systems. Partial molar quantities, Gibbs-Duhem equation.
• Balance in one-component system, Clapeyron equal. Clausius-Clapeyron equal, application.
• Equal constant of chemical reaction, its dependence on temperature.
• Gibbs phase law, application. Thermodynamic analyse of two-component system, binary phase diagrams.
• Rules of representation 3- and 4-component systems, ternary phase diagrams.
• Richardson-Jeffes’s diagram, mutual stability of oxides.
• Reduction of oxides by hydrogen and carbon oxide. Reduction of oxides by carbon. Stability of oxides with different partial pressure of oxygen.