Thermodynamic functions. Distance from equilibrium. Rate constants, transition state theory, influence of surface area and temperature, potential barrier, dynamic equilibrium. Saturation index. Molar and mass fractions, ionic strength, equivalents. Stability diagrams (systems Si, Al, Fe, Mn, Cu, Zn, Pb - aqueous solutions, forms of occurrence, distribution and stability as a function of pH). Forms of occurrence of substances in water (true and colloidal solutions, suspensions, ions, complexes, ion pairs, organic complexes). Chemical and physical properties of water (structure, bonds, partial charges, dissolution of solid phases, dissolution of gases => partial pressure, Henry's law, dependence of Henry's constant on temperature). Carbonate system (basic components of the system, distribution coefficients, closed and open system, acid-base titrations, buffers, Gran's function). Acid-base reactions (water dissociation, pH, mass balances, electroneutrality condition, proton condition, acidity and alkalinity, methods of determination). Oxidation-reduction processes (electrochemical potentials, Nernst equation, redox potential, mixed potentials, electron activity, electrodes, Eh / pH diagrams). Organic substances (organic carbon, chemical oxygen demand, contaminants of organic origin, biodegradation, humic substances, etc.). Radioactive substances and isotopes in groundwater (separation, structure, fractionation, geochronology, etc.). Methods of hydrogeochemical data processing, geochemical programs. Practical examples.
Praktická hydrogeochemie
| Type of study | Follow-up Master |
|---|---|
| Language of instruction | Czech |
| Code | 541-4005/01 |
| Abbreviation | PHGCH |
| Course title | Praktická hydrogeochemie |
| Credits | 3 |
| Coordinating department | Department of Geological Engineering |
| Course coordinator | doc. Mgr. Eva Geršlová, Ph.D. |
Osnova předmětu
Povinná literatura
STUMM, W., MORGAN, J.J. Aquatic Chemistry. 3rd Edition. Wiley – Interscience Series of Texts and Monographs, New York: : John Wiley & Sons, Inc., 1996, 596 s. ISBN 0-471-51184-6
APPELO, C.A.J., POSTMA, D. Geochemistry, Groundwater and Pollution. Rotterdam: A.A. Balkema, 1993, 536 s. ISBN 04-1536-421-3
DREVER, J.I. The geochemistry of natural waters. Second edition. N.J.: Printice Hall, Englewood Cliffs, 1988, 437 s. ISBN 0-13-351396-3
WHITE, W.M. Geochemistry. 1 edition. New York: Wiley-Blackwell, 2013, 668 s. ISBN 978-0470656686
APPELO, C.A.J., POSTMA, D. Geochemistry, Groundwater and Pollution. Rotterdam: A.A. Balkema, 1993, 536 s. ISBN 04-1536-421-3
DREVER, J.I. The geochemistry of natural waters. Second edition. N.J.: Printice Hall, Englewood Cliffs, 1988, 437 s. ISBN 0-13-351396-3
WHITE, W.M. Geochemistry. 1 edition. New York: Wiley-Blackwell, 2013, 668 s. ISBN 978-0470656686
Doporučená literatura
ALBAREDE, F. Geochemistry: An Introduction. New York, NY: Cambridge University Press, 2003, 248 s. ISBN 0-521-89148-5
ROGERS, N., BLAKE, S., BURTON, K., WIDDOWSON, M., PARKINSON, I., HARRIS, N. An Introduction to Our Dynamic Planet. Cambridge, UK: Cambridge University Press, 2008, 398 p, ISBN 978-0-521-49424-3
LOLLAR, B.S. Environmental Geochemistry. Elsevier, 2005. ISBN 978-0-080-4464-3
DOMENICO, P.A., SHWARTZ, F.W. Physical and Chemical Hydrogeology, 2nd edition. New York: John Wiley & Sons, Inc., 1997, 528 s. ISBN 978-0471597629
ROGERS, N., BLAKE, S., BURTON, K., WIDDOWSON, M., PARKINSON, I., HARRIS, N. An Introduction to Our Dynamic Planet. Cambridge, UK: Cambridge University Press, 2008, 398 p, ISBN 978-0-521-49424-3
LOLLAR, B.S. Environmental Geochemistry. Elsevier, 2005. ISBN 978-0-080-4464-3
DOMENICO, P.A., SHWARTZ, F.W. Physical and Chemical Hydrogeology, 2nd edition. New York: John Wiley & Sons, Inc., 1997, 528 s. ISBN 978-0471597629