| Course Unit Code | 617-3025/01 |
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| Number of ECTS Credits Allocated | 2 ECTS credits |
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| Type of Course Unit * | Choice-compulsory type A |
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| Level of Course Unit * | Second Cycle |
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| Year of Study * | First Year |
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| Semester when the Course Unit is delivered | Summer Semester |
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| Mode of Delivery | Face-to-face |
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| Language of Instruction | Czech |
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| Prerequisites and Co-Requisites | Course succeeds to compulsory courses of previous semester |
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| Name of Lecturer(s) | Personal ID | Name |
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| MAT27 | doc. Ing. Vlastimil Matějka, Ph.D. |
| Summary |
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The subject relates to the students knowledge in the field of chemistry, physics and chemistry of solid phase and layered materials. At the beginning the lectures are focused on the explanation of the terms layered materials, intercalation and subdivision of the intercalated materials. Next part concerns with the intercalation chemistry with attention to the properties of the intercalated materials their host lattices, itercalation reactions and the methods used for the intercalation. Following lectures deal with the methods used for the study of the structure, texture and optical properties of the intercalated materials. The topics related to cation exchange phenomenon in the layered phylosilicates, organo-clay complexes, preparation and the properties of clay/(conductive polymer) composites preparation and the properties of photofuncionalized intercalated clay materials are expressed during next lectures. The introduction to pillared and porous clay heterostructures and the overview of the application potential of intercalated and pillared materials are studied in the last part of the lectures.
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| Learning Outcomes of the Course Unit |
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| The aim of the subject is to provide the information about the intercalated materials, their properties and utilization. Student will understand: i) the issues related to the intercalation chemistry, ii) the methods used for the characterization of the products of the intercalation reactions, iii) intercalation of layered silicates and iv) pillared materials. Based on the knowledge obtained within the lectures the student is able to evaluate the application potential of intercalated and pillared materials. |
| Course Contents |
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1. Layered materials, intercalation, types of the intercalated materials
2. Properties of the intercalated materials, host lattices, intercalation reactions, methods used for the intercalation.
3. The methods used for the study of the structure of the intercalated materials.
4. The methods used for the study of the texture of the intercalated materials.
5. The methods for the study of the optical properties of the intercalated materials.
6. Cation exchange capacity of clay minerals.
7. Intercalation of clay minerals, organo-clay complexes.
8. Preparation and properties of clay/polymer composites.
9. Preparation and the properties of clay/(conductive polymer) composites
10. Preparation and the properties of photofunctionable intercalated clay minerals.
11. Pillared and porous clay heterostructures.
12. Other types of the intercalated materials.
13. The examples of the practical utilization of the intercalated materials.
14. Presentation of the students’ projects.
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| Recommended or Required Reading |
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| Required Reading: |
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BERGAYA Faiza, Benny K. G. THENG a Gerhard LAGALY, ed. Handbook of clay science. Oxford: Elsevier, 2006. ISBN 0-08-044183-1.
GIL, Antonio, S. A. KORILI, Raquel TRUJILLANO a Miguel Angel VICENTE, ed. Pillared clays and related catalysts. New York: Springer, 2010. ISBN 978-1-4419-6669-8.
WHITTINGHAM, M. Stanley a Allan J. JACOBSON. Intercalation chemistry. New York: Academic Press, 1982. Materials science and technology (New York, N.Y.). ISBN 978-0-12-747380-2. |
VALÁŠKOVÁ, Marta. Vybrané vrstevnaté silikáty a jejich modifikované nanomateriály. Brno: Akademické nakladatelství CERM, 2012. ISBN 978-80-7204-811-3.
WEISS, Zdeněk a Miloš KUŽVART. Jílové minerály: jejich nanostruktura a využití. Praha: Karolinum, 2005. ISBN 80-246-0868-5.
BERGAYA Faiza, Benny K. G. THENG a Gerhard LAGALY, ed. Handbook of clay science. Oxford: Elsevier, 2006. ISBN 0-08-044183-1.
GIL, Antonio, S. A. KORILI, Raquel TRUJILLANO a Miguel Angel VICENTE, ed. Pillared clays and related catalysts. New York: Springer, 2010. ISBN 978-1-4419-6669-8. |
| Recommended Reading: |
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AUERBACH, Scott M., Kathleen A. CARRADO a Prabir K. DUTTA, ed. Handbook of layered materials. New York: Marcel Dekker, c2004. ISBN 0-8247-5349-6.
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WHITTINGHAM, M. Stanley a Allan J. JACOBSON. Intercalation chemistry. New York: Academic Press, 1982. Materials science and technology (New York, N.Y.). ISBN 978-0-12-747380-2.
AUERBACH, Scott M., Kathleen A. CARRADO a Prabir K. DUTTA, ed. Handbook of layered materials. New York: Marcel Dekker, c2004. ISBN 0-8247-5349-6.
TARABA, Boleslav. Chemická struktura pevné fáze. Ostrava: Ostravská univerzita, 1995. ISBN 8070427256. |
| Planned learning activities and teaching methods |
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| Lectures |
| Assesment methods and criteria |
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| Task Title | Task Type | Maximum Number of Points
(Act. for Subtasks) | Minimum Number of Points for Task Passing |
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| Examination | Examination | 100 | 51 |