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Macromolecular chemistry

* Exchange students do not have to consider this information when selecting suitable courses for an exchange stay.

Course Unit Code617-2074/01
Number of ECTS Credits Allocated3 ECTS credits
Type of Course Unit *Choice-compulsory type B
Level of Course Unit *First Cycle
Year of Study *Third Year
Semester when the Course Unit is deliveredWinter Semester
Mode of DeliveryFace-to-face
Language of InstructionCzech
Prerequisites and Co-Requisites Course succeeds to compulsory courses of previous semester
Name of Lecturer(s)Personal IDName
KUL37doc. Ing. Lenka Kulhánková, Ph.D.
Summary
In the course, students get acquainted with natural and synthetic macromolecular substances, their structure, properties and characterization. Furthermore, with modern trends in the production and processing of polymers, and their use in practical applications.
Learning Outcomes of the Course Unit
- define natural and synthetic macromolecular substances
- describe the structure and properties of polymeric materials
- describe the conditions of formation of polymeric substances
- describe the rheology and processing of polymers
- characterize the most important industrial polymers in terms of their production, properties and application possibilities
- clarify the degradation and stabilization of polymers
- describe composite materials with polymer matrix
Course Contents
1. Introduction to macromolecular chemistry (history, meaning, raw material base).
2. Structure and basic properties of polymers (molecular weight; polydispersity; mechanical properties; phase behavior; morphology; dissolution; swelling and rheological behavior of polymer solutions; electrical and optical properties).
3. Synthesis of polymers (polymerization, polyaddition and polycondensation).
4. Basic methods of polymer production (monomer phase polymerization; solution, suspension and emulsion polymerization).
5. Modification of polymers (chemical, mechanochemical and mechanical modification).
6. Basic natural polymers (natural rubber, polysaccharides and proteins).
7. Synthetic polymers - thermoplastics (polyolefins, fluoroplastics, styrene and acrylic polymers).
8. Thermoplastics (polyesters, polyethers, polyamides and polyurethanes).
9. Thermosets (phenoplasts, aminoplasts, resins - epoxy, polyester and silicone).
10. Synthetic rubbers (for general use, heat-resistant and oil-resistant).
11. Additives to polymers (fillers, plasticizers, plasticizers, stabilizers, blowing agents, crosslinkers, flame retardants).
12. Basics of polymer processing (injection, extrusion, blow molding, pressing and shaping).
13. Resistance, corrosion and degradation of polymers (resistance to the natural environment, mechanical resistance, resistance to chemical influences).
14. Composite materials with polymer matrix.

Contents of laboratory exercises:
- Preparation of copper silk
- Preparation of aniline formaldehyde resin
- Preparation of electrically conductive polyaniline polymer
- Preparation of cellulose triacetate
- Identification of polymers based on orientation tests
Recommended or Required Reading
Required Reading:
EBEWELE R.O. Polymer Science and Technology. CRC Press, 2000. ISBN-10: 0849389399.
DUCHÁČEK, Vratislav. Polymery: výroba, vlastnosti, zpracování, použití. Vyd. 3., přeprac. Praha: Vysoká škola chemicko-technologická v Praze, 2011. ISBN 978-80-7080-788-0.
ŠTĚPEK, Jiří, Jiří ZELINGER a Antonín KUTA. Technologie zpracování a vlastnosti plastů. Praha: SNTL - Nakladatelství technické literatury, 1989.
EHRENSTEIN, Gottfried W. Polymerní kompozitní materiály. V ČR 1. vyd. Přeložil Karel DOLEČEK, přeložil Jaroslav PADOVEC, přeložil Josef KABELKA. Praha: Scientia, 2009. ISBN 978-80-86960-29-6.
EBEWELE R.O. Polymer Science and Technology. CRC Press, 2000. ISBN-10: 0849389399.
Recommended Reading:
EHRENSTEIN, Gottfried W. Polymeric materials. Hanser Fachbuchverlag 2001. ISBN 3446214615.
MLEZIVA, Josef a Jaromír ŠŇUPÁREK. Polymery - výroba, struktura, vlastnosti a použití. 2. přeprac. vyd. Praha: Sobotáles, 2000. ISBN 80-85920-72-7.
MACHEK, Václav a Jaromír SODOMKA. Nauka o materiálu. 4. část, Polymery a kompozity s polymerní matricí. V Praze: Nakladatelství ČVUT, 2008. ISBN 978-80-01-03927-4.
EHRENSTEIN, Gottfried W. Polymeric materials. Hanser Fachbuchverlag 2001. ISBN 3446214615.
Planned learning activities and teaching methods
Lectures, Individual consultations, Experimental work in labs
Assesment methods and criteria
Task TitleTask TypeMaximum Number of Points
(Act. for Subtasks)
Minimum Number of Points for Task Passing
Credit and ExaminationCredit and Examination100 (100)51
        CreditCredit30 16
        ExaminationExamination70 35